Contribution information
Title | Limits of continuum-based models for emulsion polymerisation as a particle based systems |
Status | Not decided yet |
Type | Lecture |
Session | Reaction engineering and catalysis |
Authors |
T., Chaloupka1,
A., Zubov2,
J., Kosek3
1 University of Chemistry and Technology, Prague, Prague, Czechia
2 University of Chemistry and Technology Prague, Prague, Czechia
3 Department of Chemical Engineering, UCT Prague, Prague 6, Czechia
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Uploaded abstract | link |
Brief content | Seeded emulsion consists of two phases – continuous aqueous phase and dispersed polymer particles. During polymerisation radicals are created in the aqueous phase, then attack some polymer particle, where it propagates via water-insoluble monomer. There are two attributes related to emulsion polymerisation resulting from the nature of the process. First, non-equal distribution of reaction loci within a particle (higher near the edge) and, second, strict separation of particles, which makes impossible a reaction of a radical from one particle with radical or polymer in another particle. Both attributes result in limitations of some mathematical models and we will address these limitations by comparing a kinetic ODE model and kinetic Monte Carlo model. |
ID | 245 |